Firstly, please remember that Print Check is only available in the Shaper module.
Students may possibly see the Print Check tab disabled in Shaper, like this:
This is because it has been explicitly turned off by a teacher at your school.
In the Teacher Dashboard, if you go to the Privacy & Integration Settings page, you will see an option for Number of print requests a student can make at once.
If this option is set to None, then the Print Check tab in the app will be disabled for all students.
For more information about how print checking works, please read here.